![]() All four of these electrons are counted in both the carbon octet and the oxygen octet, so that both atoms are considered to obey the octet rule. ![]() In carbon dioxide each oxygen shares four electrons with the central carbon, two (shown in red) from the oxygen itself and two (shown in black) from the carbon. The electrons shared by the two atoms in a covalent bond are counted twice, once for each atom. The valence electrons can be counted using a Lewis electron dot diagram as shown at the right for carbon dioxide. Other rules exist for other elements, such as the duplet rule for hydrogen and helium, and the 18-electron rule for transition metals. The rule is especially applicable to carbon, nitrogen, oxygen, and the halogens although more generally the rule is applicable for the s-block and p-block of the periodic table. The octet rule is a chemical rule of thumb that reflects the theory that main-group elements tend to bond in such a way that each atom has eight electrons in its valence shell, giving it the same electronic configuration as a noble gas. The bonding in carbon dioxide (CO 2): all atoms are surrounded by 8 electrons, fulfilling the octet rule. JSTOR ( October 2023) ( Learn how and when to remove this template message).Unsourced material may be challenged and removed. Please help improve this article by adding citations to reliable sources. This article needs additional citations for verification. (2012, December 18) Valence Electrons and the Periodic Table. If the valence shell of an element is full, such as with a noble gas, then the element does not want to gain or lose an electron.įor example, alkali metals, which all have a valency of 1, want to lose that one electron and are likely to form ionic bonds (such as in the case of NaCl, or table salt) with a Group 17 element, which has a valency of 7 and wants to gain that one electron from the alkali metal (Group 1 element) to form a stable valency of 8.įor more on valence electrons and how they're related to the periodic table, I strongly recommend this video:Ĭitations: Tyler Dewitt. ![]() They determine how "willing" the elements are to bond with each other to form new compounds. Valence electrons are responsible for the reactivity of an element. You can easily determine the number of valence electrons an atom can have by looking at its Group in the periodic table.įor example, atoms in Groups 1 and 2 have 1 and 2 valence electrons, respectively.Ītoms in Groups 13 and 18 have 3 and 8 valence electrons, respectively. Valence electrons are the electrons present in the outermost shell of an atom. To form a covalent bond, one electron from the halogen and one electron from another atom form a shared pair.įor example, in #"H–F"#, the dash represents a shared pair of valence electrons, one from #"H"# and one from #"F"#. To form an ionic bond, a halogen atom can remove an electron from another atom in order to form an anion (e.g., #"F"^"-", "Cl"^"-"#, etc.). They have one less electron configuration than a noble gas, so they require only one additional valence electron gain an octet. The most reactive nonmetals are the halogens, e.g., #"F"# and #"Cl"#. Nonmetals tend to attract additional valence electrons to form either ionic or covalent bonds. They need to lose only one or two valence electrons to form positive ions with a noble gas configuration. ![]() The most reactive metals are those from Groups 1 and 2. Generally, elements in Groups 1, 2, and 13 to 17 tend to react to form a closed shell with a noble gas electron configuration ending in #ns^2 np^6#. Elements whose atoms have the same number of valence electrons are grouped together in the Periodic Table. ![]()
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